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How to set bold small-caps in a table header?

I've defined a command like so:

\makeatletter\newcommand{\ion}[2]{#1$\;$\textsc{\rmfamily\@roman{#2}}\relax}\makeatother

The purpose is to typeset an ionization state with small caps roman numerals (e.g., \ion{He}{2}). This works fine in the main body of my text, and in table footnotes, but in the header columns it fails. Here's an example:

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Any suggestions for how to fix this?


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